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DEFINITION
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PURPOSE OF TEST
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NORMAL LEVELS
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SOURCES
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Alkalinity
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A measure of a
stream’s ability to resist changes in pH. It is often referred to as the buffering capacity of a
stream, which is important because it allows a stream to neutralize acidic
pollution or contamination.
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It is the best
measure of a stream’s sensitivity to acid inputs. Abrupt changes in alkalinity may
signify pollution. Without
neutralizing capacity, any acid added to a stream would cause an immediate
change in pH.
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Levels between 100
and 200 mg/L provide ideal buffering within a stream; endurable pH levels may
be maintained at this level of alkalinity, and aquatic life may be protected
from acidic shock; this occurs when there is a sudden decrease in pH that
aquatic life cannot rapidly adapt to in order to survive.
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Is greatly
determined by the type of underlying bedrock and soil through which the water
flows. High values may be caused
by sewage and livestock waste.
Values in excess of what bedrock types indicate as normal may be the
result of sewage, livestock wastes, and/or the production of concrete. Very low readings may be due to heavy
rains or other acidic contamination.
Abrupt changes may signify pollution.
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Aluminum
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An element that
rarely occurs in solution in natural water in concentrations greater than a
few tenths or hundreds of a milligram per liter. The exceptions are mostly waters of a very low pH.
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The dissolved
aluminum in waters having low pH has a negative effect on fish and some other
forms of aquatic life.
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Water having a pH
below 4.0 may contain several thousand milligrams of aluminum per liter. Occasional reported concentrations of
1.0 mg/L or more, having a neutral pH, and no unusual complexing ions,
probably represents particulate matter.
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Elevated aluminum
concentrations have been observed in runoff and lake waters in areas affected
by low pH precipitation.
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Calcium
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The most abundant
of the alkaline-earth metals and is a major constituent of many common rock
minerals. It is an essential
element for plant and animal life and is a major component of the solutes in
most natural water.
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The average
concentration of calcium in river water is between 13.4 and 14 mg/L.
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Calcium is
generally a predominant cation in river waters.
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Chloride
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The value of
chloride, for the purpose of water quality monitoring, is its role as an
indicator substance. Traced to
its source, it often leads to other more serious problems.
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Levels of 0-16 mg/L
are considered normal, levels of 17-36mg/L are suspect, and levels greater
than 36 mg/L are considered problematic. Above 400 mg/L may be toxic to aquatic life.
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Is contained in
rock and soil, the wastes of animals and stems from the decomposition of
living things. Sources of
abnormal readings could be from street salting, sewage, failing septic
systems, landfills, and various industries.
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Dissolved Oxygen
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It is absorbed from
the atmosphere and from the result of photosynthesis. Its concentration is related to the
temperature and density of the water.
A stream with running water will contain more dissolved oxygen than
still water. Cold water holds
more oxygen than warm water.
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If more oxygen is
consumed than produced, some organisms die due to low oxygen levels.
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Some organisms
require more oxygen than others and are more sensitive to sudden changes in
DO than others. DEP standards
are based upon the classification of the water body. Dissolved oxygen levels of at least
4-5 mg/L are needed to support a wide variety of aquatic life. Trout require at least 7 mg/L
dissolved oxygen for unimpaired production. Spikes in dissolved oxygen may indicate sources of
pollution. Because of its
churning, running water will contain more DO than still water. Very few species can exist at levels
below 3 mg/L.
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Wastewater from
sewage treatment plants, storm water runoff, and failing septic systems. Low values can sometimes be
attributed to poorly-shaded water, which can cause warming. Plant life also influences the content. In areas of dense algae growth, DO
levels are likely to drop significantly at night and increase excessively
during the day. Respiration by
aquatic animals and various chemical reactions consume DO in water.
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Iron
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Iron is an
essential element in the metabolism of animals and plants. Although iron is the second must
abundant metallic element on earth, concentrations in water are generally
small.
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A recommended upper
limit for iron in public water supplies is 0.3 mg/L. Although iron is the 2nd
most abundant metallic element on earth, concentrations in water are
generally small. If present in
water in excessive amounts, however, it forms red oxyhydroxide precipitates.
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Lower pH and higher
iron concentration can occur in coalmine drainage water.
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Manganese
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It’s an
essential element for both plant and animal life, and tends to deposit black
oxide stains.
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It is an
undesirable impurity in water supplies.
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The recommended
upper limit in public water supplies is 0.05 mg/L. Manganese is often present to the extent of more than 1
mg/L in streams that have received acid drainage from coalmines.
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Acid drainage from
coal mines.
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Nitrate
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One of the forms of
nitrogen found in aquatic ecosystems.
Others include ammonia and nitrite. Nitrate is the most completely oxidized state of nitrogen
commonly found in water, and is the most readily available state utilized for
plant growth. Since nitrate
plays a key role in stimulating plant growth, it is heavily used as a
nutrient component of fertilizer.
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High nitrate levels
combined with phosphates cause excessive plant and algae growth, a
deteriorating process called eutrophication. It causes changes in the types of plants and animals
living in a stream, may lead to low dissolved oxygen, and may cause
temperature increase. Higher
concentrations in water are unsafe to drink due to the possible presence of
altered forms of nitrite, which may cause serious illness to both humans and
wildlife.
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Unpolluted waters
normally have less than 1 mg/L.
The DEP water quality standard is 10 mg/L.
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Fertilizer runoff
resulting from improper application, failing septic systems, animal wastes
from livestock confinement or manure storage areas, decomposing organic
matter, and industrial discharges containing corrosion inhibitors.
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Nitrogen
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Exists in several
forms in the aquatic environment.
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At higher
concentrations, water is unsafe to drink due to the possible presence of
altered forms of nitrite, which may cause serious illness to both humans and
wildlife.
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Unpolluted water
will normally have a nitrate level less than 1 mg/L. The DEP water quality standard for
nitrate is 10 mg/L.
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Sources of
abnormally high readings could come from fertilizer runoff resulting from
improper application, human and animal wastes from failing septic systems and
livestock confinement areas, and decomposing organic matter.
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Ortho-Phosphate
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Just one form of
phosphorus found in natural waters. Other forms of phosphorus found in natural
waters that have not been tested include polyphosphates, and
organically-bound phosphates
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This is the tested
form of phosphate because it is the form of phosphate used in fertilizer and
applied to agricultural fields and residential lawns. Like nitrates, phosphates negatively
impact water by causing accelerated rates of eutrophication.
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Phosphate levels
below 0.03 mg/L are generally considered to be unpolluted. Levels between 0.003 and 0.1 mg/L are
sufficient to stimulate plant growth.
The critical level for avoiding accelerated eutrophication is 0.1
mg/L. Levels above 0.1 mg/L are
considered problem areas. There
has not been a standard set for safe drinking water because humans can
tolerate extremely high levels before it even takes effect on the digestive
system.
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Phosphates
naturally found in water are derived from decomposing organic material and
leaching of phosphorus-rich bedrock.
Sources of abnormally elevated readings would come from fertilizer
runoff, human and animal waste from failing septic systems, sewage treatment
plants, livestock confinement areas, mass quantities of decomposing organic
matter, industrial effluent, and detergent wastewater. Detergent wastewaters are responsible
for about half of the phosphates polluting natural waters.
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PH
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It is based on a
scale from 0 to 14. On this
scale, 0 is the most acidic value, and 14 is the most alkaline value. Seven would be neutral. A change of 1 pH unit represents a
10-fold change in acidity or alkalinity. The range of freshwater is 2-12.
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Variations in pH
affect chemical and biological processes in water. Low pH increases availability of metals and other toxics
for intake of aquatic life. It
is critical to survival, growth, and reproduction of fish and macro
invertebrates to maintain a constant pH. Exposure to very low or high pH may cause death or
reproductive problems for fish and other aquatic life. Slight variations of pH on a daily
basis or major changes over time can cause extreme stress to that species.
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A range from 6.5 to
8.2 is optimal for most organisms.
The DEP standard is between 6 and 9.
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Dissolved minerals
from rocks and soil contribute to pH, but reaction of dissolved carbon
dioxide with water is a major determinant. Sources of abnormal acidic readings include acid mine
drainage, industrial effluent, acid rain, sewage lagoons, and livestock
containment areas. Sources of
alkaline conditions include concrete plants, water treatment plants, and raw
sewage
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Phosphates
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Organic phosphates
are associated with living material and can be used by animals. It is an essential nutrient for plant
and animal growth.
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Slight increases
may cause numerous undesirable effects, such as: accelerated plant growth, algae
blooms, low dissolved oxygen levels, and death of certain aquatic organisms.
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Phosphate levels
below 0.03 mg/L are generally considered to be unpolluted. Levels between 0.03 and 0.1 mg/L are
sufficient to stimulate plant growth.
The critical level for avoiding severe impact is 0.1 mg/L.
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Wastewater from
sewage treatment plants, fertilizer runoff, faulty septic systems, livestock
confinement and manure storage facilities.
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Phosphorus
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It’s an
essential nutrient for plant and animal growth, and is normally in short
supply in natural systems. There
are many forms of phosphorus that exist, but pure elemental phosphorus is
rare. Organic phosphates are
associated with living material and can be used by animals, whereas inorganic
phosphates are forms required by vegetation. It may be dissolved or suspended in a water body.
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Slight increases
may cause numerous undesirable effects, such as accelerated plant growth,
algae blooms, low dissolved oxygen, and the death of certain aquatic
organisms.
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Phosphate levels below
0.03 mg/L are generally considered to be unpolluted. Levels between 0.03 and 0.1 mg/L are
sufficient to stimulate plant growth.
The critical level for avoiding severe impact is 0.1 mg/L.
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It naturally exists
in rocks, soil, and animal wastes.
It can also come from wastewater from treatment plants, fertilizer
runoff, faulty septic systems, livestock confinement areas or manure storage
facilities, and detergent wastewater.
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Potassium
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An essential
element in both plants and animals.
The element is present in plant material and is lost by crop
harvesting and removal, as well as by leaching and runoff acting on organic
residues.
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Maintenance of
optimum soil fertility entails providing a supply of available potassium.
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Concentrations more
than a few tens of mg/L are unusual except in water having high
dissolved-solids concentrations.
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Sources of abnormal
readings: Biological factors may be important in controlling the availability
of potassium for solution in river and groundwater. At times of relatively high water discharge, many streams
carry potassium concentrations nearly as high as they do at times of low
discharge. This may be the
result of soil leaching by runoff.
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Redox Potential
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The
measure (in volts) of the affinity of a substance for electrons
- its electronegativity - compared with hydrogen, which is
set to zero. It is determined by the presence of
inorganic dissolved solids, such as salts. Substances more
strongly electronegative than hydrogen habe positive redox
potentials.
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Specific
Conductance
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The ability of
water to conduct an electrical current, which is the measure of the quantity
of ions in the water (typically measured in micromhos). It is determined by the presence of
inorganic dissolved solids, such as salts.
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Measurements
outside the normal range for a stream may indicate the presence of a
contaminant. These testing
parameters serve as a check to make sure pollutants are not being overlooked
that are not part of the regular sampling routine.
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U.S. rivers range
from 150 to 500 micromhos/cm.
Conductivity beyond this range may not be suitable for certain fish
and macro invertebrates. Almost
any pollutant may cause a value falling outside the normal range for a
site. Distilled water ranges
from 0.5-3 micromhos/cm, whereas industrial effluent may be as high as 10,000
micromhos/cm.
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Geologic formations
have a great impact on the specific conductance of a stream. Carbonate bedrocks often yield high
conductivity. Discharges to a
stream can impact conductivity.
Point-source discharges, as well as storm
water runoff, may
be contributors to excessive readings.
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Sulfate
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Sulfur is commonly
found as a component of sedimentary and igneous rocks in the form of metallic
sulfides. Sulfides are oxidized
upon contact with aerated water, producing sulfate ions in solution.
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Excessive levels in
water may cause illness.
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The drinking water
standard for sulfate is 250 mg/L.
Beyond this point, sulfate levels may cause illness in humans.
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The combustion of
fuel and ore-smelting processes are major anthropocentric causes of sulfate
found in natural waters.
Sulfides may also be present in soils that are oxidized through
natural processes or organic waste treatment. Sulfate also occurs in evaporite sediments, such as
anhydrite and gypsum. Excessively
high sulfate readings are often associated with mine drainage. The oxidation of minerals like pyrite
is the main culprit. High
sulfate, as well as chloride concentrations, may be found in residual runoff
from irrigated areas due to water that was lost through evapotranspiration.
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Suspended Solids
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Includes all
particles in water that will not pass through a filter having openings of
0.45 microns in diameter.
Typically, suspended solids include items such as soil, algal cells,
and plant particles.
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High levels may
smother aquatic organisms.
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It is recommended
that suspended solids not exceed 25 mg/L. Unpolluted streams usually have concentrations less than
10 mg/L.
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High suspended
solids may occur below sewage treatment plants, construction sites and farms
where erosion rates are high, various industries, and below algal-choked
lakes.
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Temperature
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A key determinant
of what species can survive in a particular environment.
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Temperature
preferences vary widely among species and all species are negatively impacted
by rapid fluctuations in temperature.
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Desired
temperatures depend on the desired use of the water body. Life and reproductive necessities for
trout are the target standards for water temperature. Growth is impaired in Brook Trout at
temperatures above 19 degrees Celsius.
Death will occur above 24 degrees. DEP standards dictate that a temperature no greater than
19 degrees Celsius is required to be a high quality, cold-water fishery. .
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Discharges of
coolant and wastewaters from industrial or utility plants, runoff from heated
surfaces, and lack of stream cover to provide shade are among the top sources
of thermal pollution.
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Total Hardness
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Calcium, magnesium,
and carbonate are the major components of hardness, which is the amount of
dissolved minerals in water.
Minerals are dissolved from bedrock and soil as water passes through
them. The calcium component of
hardness is very important to aquatic life, as it is used for the cell walls
of plants and the shells and bones of aquatic organisms. Hard water aids buffering capacity,
as heavy metals and other toxic compounds may be more detrimental in soft
water than in hard water.
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Tests usually
measure the calcium and magnesium carbonate concentration in a water
sample. High levels of hardness
can cause precipitation and deposition of calcium carbonate on the stream
bottom, which disrupts normal stream activity. Water with high hardness may also cause
plumbing problems.
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Optimal values of
hardness of aquatic life range from 100 to 200 mg/L. At levels above 250 mg/L, calcium
carbonate will begin to precipitate. Hardness values should be slightly
higher than alkalinity values.
If there is a major difference between the two values, chloride and
sulfate ions may be present.
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High hardness
values are often associated with limestone formations.
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Total Solids
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They include
dissolved solids, suspended, and settleable solids. Dissolved solids are small enough to pass through a filter
with holes about 2 microns (or 0.002 cm) in diameter. They are measured in mg/L and include
silt, clay particles, plankton, algae, fine organic debris, and other particles.
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It is tested
because: aquatic organisms may shrink or swell depending on level of solids;
organisms in low level solids water might swell due to water moving into its
cells; and because this effect may cause organisms to float or sink in water
columns to a level at which it is not adaptable.
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They come from
industrial discharges, sewage, fertilizer, road runoff, and soil erosion.
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Turbidity
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It is a measure of
water clarity that measures how much the passage of light is restricted by
suspended particles. It may
affect the color of water.
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We test it because:
high levels may increase temperatures; it may lower dissolved oxygen levels;
it can reduce photosynthesis; it can clog fish gills, which lowers growth
rate and resistance to disease; and it can smother fish eggs and macro
invertebrates.
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It comes from
suspended particles that include soil, algae, plankton, microbes, and other
substances.
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Zinc
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It is essential in
plant and animal metabolism.
Modern industry has several applications for zinc and has helped to
widely distribute it in water supplies.
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Zinc can be
considered an undesirable contaminant for some species of aquatic life.
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Five mg/L is
considered the upper limit for zinc because above this limit can be detected
by taste. Concentrations in river
water range from 5 to 45 mg/L.
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Water is not a
significant source of the element in the dietary sense. It has about the same abundance in
crustal rocks as copper or nickel, and is thus fairly common. High levels in streams can mean that
there is acid mine drainage.
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